Introduction
A glass is an inorganic nonmetallic material that does not have a crystalline
structure. Such materials are said to be amorphous. Typical glasses
range from the soda-lime silicate glass in soda bottles to the extremely high purity
silica glass for optical fibers.
The main constituent of Glass is Silicon dioxide. The most common
form of silica used in glassmaking has always been sand.
Sand by itself can be fused to produce glass but the
temperature at which this can be achieved is about 1700° C.
Adding other chemicals to sand can considerably reduce the temperature
of the fusion. The addition of sodium carbonate (Na2O), known as soda ash,
in a quantity to produce a fused mixture of 75% silica (SiO2) and 25% of
sodium oxide (Na2O), will reduce the temperature of fusion to about 800° C.
However, a glass of this composition is water soluble and is known as water
glass. In order to give the glass stability, other chemicals like calcium oxide
(CaO) and magnesium oxide (MgO) are needed. The raw materials used for
introducing CaO and MgO are their carbonates CaCO3 (limestone) and MgCO3 (dolomite),
which when subjected to high temperatures give off carbon dioxide leaving the
oxides in the glass.
Borosilicate glass:
Borosilicate glasses are composed mainly of silica (70-80%)
and boric oxide (7-13%) with smaller amounts of the alkalis
(sodium and potassium oxides) and aluminum oxide. They are characterized by
the relatively low alkali content and consequently have good chemical durability
and thermal shock resistance. Thus they are permanently suitable for process
plants in the chemical industry, for laboratory apparatus, for various high intensity lighting applications and asglass fibers for textile and plastic reinforcement. In the home they are familiar in the form of ovenware and other heat-resisting ware e.g Pyrex.
Properties
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MECHANICALLY STRONG
Has great inherent strength. Weakened only by surface imperfections,
which give everyday glass its fragile reputation.
Special tempering can minimize surface flaws.
HARD
Surface resists scratches and abrasions.
ELASTIC
Gives under stress - up to a breaking point -
but rebounds exactly to its original shape.
CHEMICAL CORROSION- RESISTANT
Affected by few chemicals. Resists most industrial and food acids.
THERMAL SHOCK- RESISTANT
Withstands intense heat or cold as well as sudden temperature changes.
HEAT - ABSORBENT
Retains heat, rather than conducts it. Absorbs heat better than metal.
OPTICAL
- REFLECTS
- BENDS
- TRANSMITS
- ABSORBS light with great accuracy.
ELECTRICAL INSULATING
Strongly resists electric current. Stores electricity very efficiently.
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